Aims & Scope

Journal of the Geological Society of Korea - Vol. 57 , No. 4

[ Article ]
Journal of the Geological Society of Korea - Vol. 57, No. 4, pp. 523-544
Abbreviation: J. Geol. Soc. Korea
ISSN: 0435-4036 (Print) 2288-7377 (Online)
Print publication date 31 Aug 2021
Received 10 Mar 2021 Revised 04 May 2021 Accepted 29 Jul 2021
DOI: https://doi.org/10.14770/jgsk.2021.57.4.523

Reviews on the Paleozoic-Mesozoic granitoids and sedimentary rocks in North Korea
Yan-Bin Zhang1, 2 ; Ming-Guo Zhai1, 2, 3, ; Fu-Yuan Wu1, 2, 3 ; Xiao-Hui Zhang1, 2 ; Qiu-Li Li1, 2, 3 ; Peng Peng1, 2, 3 ; Lei Zhao1, 2 ; Li-Gang Zhou1, 2
1State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
2Innovation Academy for Earth Science, Chinese Academy of Sciences, Beijing 100029, China
3College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

북한지역 고생대-중생대 화성암 및 퇴적암에 대한 종합검토
Yan-Bin Zhang1, 2 ; Ming-Guo Zhai1, 2, 3, ; Fu-Yuan Wu1, 2, 3 ; Xiao-Hui Zhang1, 2 ; Qiu-Li Li1, 2, 3 ; Peng Peng1, 2, 3 ; Lei Zhao1, 2 ; Li-Gang Zhou1, 2
1State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences
2Innovation Academy for Earth Science, Chinese Academy of Sciences
3College of Earth and Planetary Sciences, University of Chinese Academy of Sciences
Correspondence to : +86-10-82998570, E-mail: mgzhai@mail.iggcas.ac.cn

Funding Information ▼

Abstract

The lack of relevant geological information and data in North Korea greatly hampers understanding of the geological evolution of the Korean Peninsula. This paper reviews the studies of the Paleozoic-Mesozoic granitoids and sedimentary rocks in North Korea. (1) Phyongnam Basin comprises lower Paleozoic Hwangju Supergroup (Hwangju and Bopdong Groups) and Upper Paleozoic Pyongan Supergroup. δ13C values in the Cambrian Hwangju and lower Bopdong Groups fluctuate little (-4~+4‰), but frequently. (2) The middle Paleozoic Imjin Group only distributed in the southern margin of the Phyongnam Basin and deposited in Late Devonian. Similar detrital zircon age spectra of representative Paleozoic sequences in the Korean Peninsula and the North China Craton indicates that these two tectonic units might experience similar tectonic evolution, and the Imjingang Belt might not be the eastward extension of the Qinling- Dabie-Sulu Collisional Belt. (3) The late Permian volcano-sedimentary strata Tuman Group is well developed in the Tumangang Belt and Kwanmo Submassif. (4) The Mesozoic sedimentary strata are mostly developed in continental faulted basins, and consist of lower Jurassic Taedong, upper Jurassic-lower Cretaceous Jasong, and lower-upper Cretaceous Taebo Systems. The volcanic activity within 136-110 Ma in North Korea was significant. (5) Phanerozoic granitoids and related igneous rocks with age ranges of 265-213 Ma, 199-163 Ma to 136-83 Ma are widely distributed in North Korea. Except for the absence of early Cretaceous magmatism (136-110 Ma) in South Korea, other magmatic events can be comparable to those in South Korea. (6) The age patterns and geochemical features of Phanerozoic granites in the Tumangang Belt and Kwanmo Submassif are similar to those of the eastern part of the Central Asian Orogenic Belt. (7) The Triassic granitoids in North Korea were most likely formed in intracontinental rift environment and were also influenced by adjacent blocks from the north and south of the Korean Peninsula.

초록

북한에 대한 지질학적 정보의 부족은 한반도의 지질학적 진화를 이해하는데 큰 장애가 되고 있다. 본 논문에서는 북한의 고생대-중생대 화강암류와 퇴적암에 대한 연구를 종합 검토하였다. (1) 평남분지는 하부의 고생대 초기 황주누층군(황주층군과 법동층군)과 상부의 고생대 후기 평안누층군으로 구성되어있다. 캠브리아기 황주층과 하부 법동층의 δ13C는 변화폭은 작으나(-4~+4‰) 자주 변화한다. (2) 고생대 중기 임진층군은 평남분지 남쪽 경계부에서만 나타나며 후기 데본기에 퇴적되었다. 한반도와 북중국판의 대표적인 고생대 퇴적층내 쇄설성 저어콘 연령분포형태가 유사한 사실은 한반도와 북중국판이 유사한 지구조 진화를 경험하였음을 지시하며 임진강대가 친링-다비-수루 충돌대의 연장이 아님을 지시한다. (3) 페름기 후기 화산-퇴적층군인 두만층군이 두만강대와 관모육괴에 퇴적되었다. (4) 중생대 퇴적층은 대부분 대륙내에 단층작용에 의해 형성된 분지내에 발달했으며 쥐라기 초기 대동계, 쥐라기 후기-백악기 초기 자성계 그리고 백악기 초-후기에 해당하는 대보계로 구성되어있다. 136-110 Ma 시기 동안 북한에서는 화산활동이 활발하게 일어났다. (5) 북한의 현생 화강암류와 그에 관련된 화성암들이 265-213 Ma, 199-163 Ma,136-83 Ma에 광역적으로 형성되었다. 남한의 현생 화성작용은 백악기 초기(136-110 Ma)에 해당하는 화성작용이 없는 것을 제외하고는 북한의 화성작용에 잘 대비된다. (6) 북한 두만강대와 관모육괴내 현생 화강암들의 연령분포형태와 지화학 특성이 중앙아시아조산대의 동부에 나타나는 현생 화강암들의 연령 패턴과 지화학 특성과 유사하다. (7) 북한의 트라이아스기 화강암류는 대륙내 열개 환경에서 형성되었으며 한반도의 북쪽과 남쪽 인근 지판들의 영향을 받았을 것으로 생각된다.


Keywords: Paleozoic-Mesozoic, granitoids, sedimentary rocks, North Korea
키워드: 고생대-중생대, 화강암류, 퇴적암, 북한

1. Introduction

The Korean Peninsula (KP) is situated at the eastern margin of the North China Craton (NCC; or Sino Korean Craton), with a complex and long geological history that extends deep into the Paleoarchean (~3600 Ma). It is generally considered that the KP can be divided into six tectonic provinces from north to south, i.e., the Tumangang Belt, Nangrim Massif (including Kwanmo and Nangrim Submassif), Imjingang Belt, Gyeonggi Massif, Okcheon Belt and Yeongnam Massif, respectively (Fig. 1a). The Paleozoic Phyongnam and Taebaeksan Basins are located within the Nangnim Massif and Okcheon Belt, respectively (Choi, 2018).


Fig. 1. 
(a) Tectonic units of the Korean Peninsula (revised after Paek et al., 1996). (b) Distribution of Paleozoic-Mesozoic sediments in North Korea (modified after Paek et al., 1996).

It has been long discussed for the tectonic relationship between the KP and China due to their strong affinities (e.g., Zhai, 2016; Zhai et al., 2016, 2019). However, the absence of relevant geological information and data on North Korea (NK) greatly hampers our understanding of the geological history of the KP, and it’s general tectonic framework in the NE Asia. In this paper, we report some new achievements and give a summary on the Paleozoic-Mesozoic magmatism and sedimentation in NK, which will shed a light on the Paleozoic-Mesozoic evolution of the KP, even of the NE Asia.


2. Paleozoic sediments

The Paleozoic sedimentary strata in NK are mainly developed in the Tumangang Belt, Hyesan-Rowon Basin and Hwaphyong-Jasong-Wiwon areas in the Nangrim Massif, and the Phyongnam Basin (Fig. 1b). Among them, the Paleozoic strata in the Phyongnam Basin have the largest outcropping area and relatively complete stratigraphic sedimentary sequence, which consist of the Lower Paleozoic (Cambrian-Middle Ordovician) and Upper Paleozoic (Late Carboniferous-Early Triassic) strata (Fig. 2). Between these two strata, an unconformity was existed, which indicates a deposition break more than 100 Myr. Rare Middle Paleozoic sediments are only distributed in the southern margin of the Phyongnam Basin and Imjingang Belt. The Tumangang Belt and Kwanmo Submassif lack the Lower Paleozoic strata, and characterized by development of the Late Paleozoic volcanic sedimentary formations.


Fig. 2. 
The Paleozoic stratigraphic framework in North Korea.

2.1 Phyongnam Basin

The Phyongnam Basin in the Nangrim Massif is featured by Neoproterozoic to Triassic strata depositing unconformably on the Archean and Early Paleoproterozoic basement. The Lower Paleozoic sediments of the Hwangju Supergroup in the basin is exclusively of marine origin with subordinate siliciclastic rocks. The maximum thickness of this supergroup could reach 3,000 m, with an average thickness of 1,200-1,500 m. The Hwangju Supergroup was subdivided into the lower Hwangju and upper Bopdong Groups (Paek et al., 1996; Park, 2012) the former one is dominated by marine terrigenous clastic deposits, while the later one is occupied by carbonate rocks.

The Hwangju Group is subdivided into conformably laid series in ascending order, namely the Pyongsan, Junghwa, Hukgyo and Rimchon Formations. The Pyongsan Formation is mainly composed of phosphate siltstones, carbonaceous slates, nodular phosphorites and Dolomites. Among them, the phosphorous and sulphide-bearing black slate at the bottom of this formation were considered as the boundary layer (Kim et al., 2018). The Junghwa Formation consists of sandstone, siltstone, slate, and carbonate rock, with phosphate bearing siltstone at the bottom. The Hukgyo Formation is made up of terrigenous clastic rocks locally interlayered with carbonates. The Rimchon Formation is mainly composed of black phyllite with a limestone interlayer at the lowest part. The hsuapis coreanicus and redlichia belts occurred in the Pyongsan and Junghwa Formations, respectively, showing that these two formations should not be lower than Stage 3 and 4 of the Cambrian (Kim et al., 2018). Carbon isotope study show that the δ13C values in the Pyongsan Formation range from -3.1‰ to 0‰, Junghwa -4.7‰ to +2.0‰, Hukgyo -1.0‰ to +2.4‰, and Rimchon -2.6‰ to +0.4‰ (Kim et al., 2016, 2018). Compared to the global carbon isotope of carbonate rocks, the Pyongsan, Junghwa and Hukgyo Formations belong to Stages 3-4 of Cambrian, and the Rimchon Formation is around the boundary of Series 2 and Miaoling Series, respectively (Kim et al., 2018). The positive carbon excursion in the upper Junghwa and Hukgyo Formations and negative in the lower Rimchon Formation are comparable to the global events of the mIngxinsi carbon isotopic excursion and red-lichiid-olenellid extinction carbon isotopic excursion, respectively (Kim et al., 2018).

The Bopdong Group is subdivided into the Mujin, Kophung, Singok, Mandal, Sangsori, Koksan and Wolyang Formations, with a thickness of about 1,000 m. The first two formations are assigned to the Late Cambrian, middle three are Ordovician, and the last two are Silurian (Paek et al., 1996). The Mujin Formation is mainly composed of clay limestone, manganese-bearing limestone and layered limestone. The Kophung Formation is successive sequences of lower dolomite and limestone and upper dolomite and limestone. The Singok Formation consists mainly of dolomite with minor limestone. The Mandal Formation consists of lower limestone and upper dolomite. The Sangsori Formation consists of dolomite interlayered with mudstone, shale, and limestone. The Silurian Koksan and Wolyang Formations are only sporadically exposed in the Singye, Koksan and Popdong areas. The Koksan Formation is composed of siltstone, mudstone, shale and limestone, with a layer of siltstone at the bottom. The Wolyang Formation is mainly composed of limestone, with minor mudstone and dolomitic limestone (Paek et al., 1996). Carbon isotope study shows that the δ13C values in the Mujin Formation range from -1.3‰ to 0.4‰ and the Kophung Formation displays -1.0‰ to +2.4‰ (Kim et al., 2018). Synthetically, the Kophung Formation belongs to the Furong Series of Cambrian, and the positive carbon excursion in the middle of the Kophung Formation is comparable to the global events of the Steptoean positive carbon isotopic excursion (Kim et al., 2018). Combing with biostratigraphy and regional stratigraphic correlation, the Bopdong Group was dated to be Cambrian Miaoling Series to Silurian (Kim et al., 2018).

The Upper Paleozoic (Late Carboniferous)-Early Triassic sediments were named the Pyeongan Supergroup, which unconformably overlies the Lower Paleozoic Hwangju Supergroup (generally Mandal Formation of the Bopdong Group), and unconformable covered by the Upper Mesozoic strata. This supergroup, approximately 1,500m thick, consists of paralic to nonmarine clastic deposits, and is characterized by high-quality coal seams and aluminous rocks. It was subdivided into the Hongjom, Ripsok, Sadong, Kobangsan and Taezhawon Formations in ascending order.

The Hongjom and Ripsok Formations were mainly composed of shale and sandstone, with thin coal measures in the upper part. The Sadong Formation (120-150 m thick) is the main coal bearing strata, and consists of shales, siltstone and sandstone with coal measures in the lower and middle parts, and aluminum rich shale and quartz sandstone in the upper part. The Kobangsan and Taezhawon Formations are mainly composed of shale and siltstone, with minor coal measures in the lower part, and silicified wood in the upper part. Above coal-bearing strata show that the paleoclimate was probably warm and arid with somewhat humid conditions.

All formations of the Pyeongan Supergroup are fossiliferous. The Hongjom Formation contains the index fusulinid fossils of the early Middle Carboniferous (Eostaffella angusta Kir, Mediocris ovalis Vissar., Millerella kasakstanica) in the lower part and those of the late Middle Carboniferous (Profusulinella, Dagmarella and Aljutovella) in the upper part. The Ripsok Formation contains the Triticites zone and plant fossils (Neuropteris pseudovata) and the Sadong, Kobangsan and Taezhawon Formations contain the index fossils of Lower to Upper Permian (e.g., Callipteris conferta, Tingia carbonica, T. hamaguchii, Lobatannularia heianensis, P. norinii) (Paek et al., 1996). On the basis of biostratigraphy, the Hongjom and Ripsok Formations were dated to be Middle and Upper Carboniferous, Sadong Formation was Lower Permian, and Kobangsan and Taezhawon Formations were dated as Upper Permian, respectively. Detrital zircons in sandstone from the Taezhawon Formation yield ages ranging from 231 Ma to 2529 Ma (Zhang, unpublished data), and the youngest group displays a weighted mean 206Pb/238U age of 231 ± 5 Ma, indicating a depositional time later than 231 Ma for the Taezhawon Formation.

2.2 Imjingang Belt

The Imjingang Belt is located between the Phyongnam Basin and the Gyeonggi Massif, separated by faults on all sides from the surrounding rocks of mainly Paleoproterozoic ages. This belt had been suggested as the eastward extension of the major Chinese suture zone (the ultra-high pressure Qinling-Dabie-Sulu Belt) (e.g., Yin and Nie, 1993; Ree et al., 1996; Oh and Kusky, 2007). However, Zhai et al. (2007) proposed that the Imjingang Belt does not exhibit any metamorphic characteristics of collisional orogenic belts. Moreover, Paek and Rim (2005) suggested the belt as a Middle Devonian to Lower Carboniferous rift zone of 15-30 km wide with tens of kilometers long in the Nangrim Massif. The belt does not extend throughout the KP with an eastern terminal in the middle peninsula.

Sedimentary strata in the Imjingang Belt were divided into the Yeoncheon Complex (or Yeoncheon Group) and Imjin System (or Imjin Group) (Cho et al., 1995; Paek et al., 1996; Ree et al., 1996). The Yeoncheon Complex was cropped out in the south of the 38th parallel in South Korea (SK), and mainly consists of metamorphosed flysch deposits (Paek et al., 1996). Detrital zircon U-Pb ages of ca. 400 Ma and 420 Ma suggested a Devonian depositional time for the Yeoncheon Complex (Cho et al., 2001, 2007; Kim et al., 2014).

However, the Imjin Group, located in the north of the 38th parallel, is a volcano-clastic sedimentary stratum with the thickness more than 2,000 m (Paek et al., 1996). It is in tectonic contact with Proterozoic or even older strata, and the rocks near the margin of the Imjingang Belt have commonly suffered strong deformation and mylonitization. The metamorphic grade of this group increases from north to south, spanning from unmetamorphosed through sericite to garnet, staurolite and kyanite zones, defining a Barrovian-type facies series. This group is about 15 to 30 km in width and several hundred kilometers in length, with the eastern and western parts that divided by the Ryesonggang fault zone. The eastern part stretches as continuous volcanoclastic sedimentary strata from the estuary of the river Ryesong through Kaesong to the Cholwon area, while the western part is distributed in the Ongjin, Kangryong and Paechon districts, with outcrops at Kangryong extending into the South Yellow Sea.

The lower part of the Imjin Group mainly consists of epicontinental-shallow water terrigenous clastic sedimentary strata with thin terrigenous intercalations, while the upper part comprises volcano-sedimentary strata with terrigenous clastic rocks. It can be divided as three formations with conformable relationships, the Anhyop, Puap and Sannyong Formations, in ascending order.

The Anhyop Formation covers an area of ~10 km2 in the northern margin of the sedimentary basin, and consists of calcareous schist, chlorite schist, phyllite, psammitic conglomerate, calcareous conglomerate, quartz sandstone and limestone. On the basis of the biostratigraphy, this formation was confirmed to be Lower-Middle Devonian (Kim, 2012). The Puap Formation consists of shale, siltstone, sandstone and conglomerate with the intercalation of carbonate rocks, which contains Middle-Late Devonian standard fossils, e.g., charophyta fossil sycidium melo var. puskowensis, and Cyrtospirife (Kim, 2012). The Sannyong Formation comprises grayishgreen massive siltstone, biotite spotted and massive siltstone, aleuritic shale, dark green shale and sandstone. Zircons from the upper siltstone and sandstone of the Puap Formation yield the youngest ages at an interval of 393 ± 8 Ma and 423 ± 5 Ma (Li et al., 2004; Zhang et al., 2018), which indicate that the Puap Formation was deposited at a maximum age of ca. 400 Ma. Moreover, the Puap Formation shows similar detrital zircon age spectra features to those of representative Paleozoic sequences in the Pyongnam and Taebaeksan Basins of the KP and Paleozoic basins in the NCC, suggesting that the NCC and KP might experience similar tectonic evolution, and the Imjingang Belt might not be the eastward extension of the Qinling-Dabie-Sulu Collisional Belt (Zhang et al., 2018).

2.3 Tumangang Belt and Kwanmo Submassif

The Upper Paleozoic Tuman Group is well developed in the Tumangang Belt (also called the Hambuk Massif), and is also exposed sporadically in the Kwanmo Submassif (Fig. 1, 3). This group consists of the Amgi, Kyeryongsan and Songsang Formations in ascending order, with an exposure area around 1,600 km2 (Paek et al., 1996; Kim, 2012).


Fig. 3. 
Sketch geological map of the Tumangang Belt and Kwanmo Massif (modified after Paek et al., 1996).

The Amgi Formation (360-950-m-thick) is mainly distributed in the Chongjin-Najin area, unconformably overlying the Precambrian rocks. It is a suit of terrigenous and volcanic clastic rocks, which consists of shale, slate, biotite siliceous schist, metamorphic sandstone, amphibolite, siliceous limestone and crystalline limestone lens. The Kyeryongsan Formation is a 570-1200-m-thick sequence of volcanic sedimentary rocks, and almost located in the Chongjin, Hoeryong and Kyongwon areas. The lower part is dominated by the tuffite and tuffaceous rocks, with minor shale, siliceous schist and limestone, whereas the upper part consists mainly of light metamorphic mafic volcanic rocks, porphyry and tuff. At the basal part, volcanic breccia was well developed, which was considered as the boundary with the underlying Amgi Formation. Limestone lenses and tuffaceous sandstones are an occasionally observed in the upper part. The Songsang Formation consists of terrigenous clastic rock, including siltstone, mudstone, shale with minor tuffaceous sandstone and limestone. Many fossils were hosted in these Formations, including fusulinids, brachiopods, crinoids, bryozoans, and plant fossils (Paek et al., 1996).

Zhang et al. (2016) reported the SIMS U-Pb age of 257 ± 3 Ma from the basaltic andesite (13NK-1) in the Kyeryongsan Formation, and suggested that this formation was formed in the Late Permian. Moreover, basaltic andesite are characterized by positive zircon εHf(t) values (+10 to +16), and fairly young TDM (262-513 Ma). Synthesizing other geochemical features, the generation of the basaltic andesite most likely involves a precursory metasomatism stage of mantle peridotites by melts from subduction-related sediments and an immediate partial melting stage (Zhang, X.H. et al., 2016).


3. Mesozoic sediments

The Mesozoic sedimentary strata are mostly developed in continental faulted basins, which caused by large faults and distributed in the long and narrow bands along the drainage areas of large rivers. Such as the Chosan, Changsong, Sinuiju Basins along the river Amnok (Yalu Jiang) were related with the Amnokgang fault zone with a NE direction, and the Anju and Pakchon Basins were related with the Jonchongang fault zone. The Mesozoic sediments consist of complex volcanic-clastic rocks, including terrigenous clastic rocks, intermediate-acid volcanic rocks, coal measures and oil shale. Usually, the Mesozoic strata consist of the Lower Jurassic Taedong, Upper Jurassic-Lower Cretaceous Jasong and Lower-Upper Cretaceous Taebo Systems. These continental strata have a variety of lithology and lithofacies, which make stratigraphic division and correlation more difficult.

The Lower Jurassic Taedong system distributed in the Jangphari, Amnokgang, Changsong, Taedonggang, Pujongang, Sinhung and Jaeronggang Basins with different names (e.g., Junggang, Songnimsan, Jangphari, Sansuri, Chongjin, Chonri, Kimpho). Similarly, the Jasong and Taebo systems are also distributed in many basins with different names.

The Amnokgang Basin, located in the Juangang-Jasong region, the west margin of the Nangnim Massif. The basin comprises the Lower Jurassic Junggang Group and Upper Jurassic-Lower Cretaceous Sinuiju Group. The Junggang Group, with an outcrop area of about 17 km2 and subdivided into the Chilhaksan, Kobidong and Odoksan Formations. The Chilhaksan Formation is composed mainly of conglomerate, in which discontinuous sandstone is intercalated. The Kobidong Formation is composed mainly of sandstone, in which conglomerate, siltstone, silty mudstone, mudstone, coaly siltstone are often intercalated. The Odoksan Formation is also mainly composed of sandstone, in which Conglomerate and siltstone are frequently intercalated. The Sinuiju Group consists of felsic-intermediate effusive rocks, its tuffaceous rocks, clastic rock and coal measures. The Kobidong Formation host many plant fossils, and representative plant fossils include Neocalamites carrelei (Zeiller) Halle, Dictyophyllum nathostii Zeiller, Clathropteris meniscoides Brongn (Paek et al., 1996). Felsic tuff from the Kobidong Formation shows zircon U-Pb ages of 136-128 Ma, and quartz porphyry also have a zircon U-Pb age of ~110 Ma (Zhang, unpublished data), conforming the early Cretaceous depositional age, which is not the Lower Jurassic age as previously thought.

To the southwest of the Amnokgang Basin, the Sinuiju Basin is distributed along the south part within the Amnogang fault zone, with the area of over 250 km2. The basin comprises the Upper Jurassic-Lower Cretaceous Sinuiju Group and Upper Cretaceous Sujin Group. The Sinuiju Group consists mostly of the clastic sedimentary rocks with minor intermediate effusive rocks, including grey, yellow fine sandstone, psammitic siltstone, mudstone, coal, conglomerate, pebbly tuff, agglomerate and andesitic porphyrite. The Sujin Group, outcropped about 13 km2, is block-shaped between the Amonkgang fault zone and the Taehwari-Ryongmun fault. It consists of reddish brown psammitic conglomerate, sandstone, siltstone, andesitic porphyrite and trachyte. The tuff and dacite from the Sinuiju Formation yield 125-116 Ma zircon U-Pb ages (Zhang, unpublished data), probably indicating that the volcanic rocks of the Sinuiju Formation were erupted in the Early Cretaceous.

In addition, the volcanic rocks outcropped in the Hyesan area were previously considered to be Late Jurassic, however, the zircon U-Pb ages of ~110 Ma (Zhang, unpublished data) indicate that they were formed in the Early Cretaceous.

Above new age data show that the Early Cretaceous was a significant period of volcanic activity in NK, with an age range of 136-110 Ma. Similarly, the Cretaceous-Paleogene igneous were also well developed in SK, and mainly developed in pull-apart or extensional basins (Kim, 1996; Lee and Chough, 1999; Chough et al., 2000). About 70% of them are scattered in and around the Gyeongsang Basin (Kim et al., 2016). Large amounts of age data show that the Cretaceous-Paleogene magmatism occurred during 113-50 Ma, and mainly in 88-80 Ma (Kwon et al., 2017 and reference therein), e.g., rhyolitic and andesitic magma in the Jinan Basin were formed at 90-89 Ma, and basaltic trachyandesite was formed at 84 Ma (Lee et al., 2020). The Cheonmasan, Udongje, Seokpo and Yujeongje Tuffs of the Buan volcanics in the Kyokpo Basin were formed at 87 Ma; the Gyeongsusan and Yeongije Tuffs of the Seonunsan volcanics in the Gyehwa Basin were formed during 87-84 Ma; the Seongsan Tuff and Gyema Rhyolite of the Beopseongpo Volcanics were formed at 86-87 Ma (Kwon et al., 2017). In general, the Cretaceous-Paleogene magmatism displays a younging trend from NK to SK (Kim et al., 2016; Wu et al., 2019).


4. Late Paleozoic-Mesozoic magmatic rocks

Phanerozoic granitoids and related igneous rocks are widely distributed in NK (Fig. 4), which is a part of the NE-SW-trending Mesozoic tectonomagmatic belt that extends from southeastern China to Far East Russia along the eastern margin of the Asian continent (Kinoshita, 1995; Kim, 1996; Cheong et al., 2002; Sagong et al., 2005; Wu et al., 2007; Zhai et al., 2016a). It was traditionally thought these granitic magmatism took place in several distinct pulses, and are classified into Permian (Phyonggang and Tumangang), Triassic (Hyesan), Jurassic (Tanchon), and Cretaceous (Amnokgang) pulses (Paek et al., 1996). Among them, the Permian Tumangang complex are thought to be concentrated in the Tumangang Belt, and the Phyonggang alkaline intrusions occurred in the south margin of the Phyongnam Basin and Imjingang Belt (Paek et al., 1996).


Fig. 4. 
Distribution of Phanerozoic granitoids in North Korea.

After more than 20 years of geological investigation and geochronological research, we have obtained 91 zircon U-Pb ages of these granitoids (Table. 1). The data show the Phanerozoic granitic magmatism in NK occurred during 265-83 Ma, and they can be temporally subdivided into 3 dominant stages: Late Permian-Triassic (265-213 Ma), Jurassic (199-163 Ma) and Cretaceous (133-83 Ma), respectively (Fig. 5).

Table 1. 
Zircon U-Pb ages of Phanerozoic granitoids in North Korea.



Fig. 5. 
Age histogram and probability diagrams for Phanerozoic granitoids in North Korea (n = 90).

4.1 Late Permian-Triassic rocks

Twenty five Late Permian-Triassic ages was obtained. Among them, three Late Permian ages (265-263 Ma) were obtained from the Rimmyongdong biotite granite and Guanmobong fo-liated granite and biotite granite, other ages are Triassic, ranging from 248 Ma to 211 Ma. These granites are mainly distributed in the Kwanmo Submassif, Nangrim Submassif and south margin of the Phyongnam Basin, and divided into calc-alkaline igneous rocks and alkaline rocks. The calc-alkaline igneous rocks include diorite, quartz diorite, tonalite, granodiorite, and monzogranite. Representative plutons are the Guanmobong batholith in the Kwanmo Submassif, the Pukjin-Unsan, Komsanyong, and Jongphyong batholithes in the Nangrim Massif.

The Guanmobong batholith in the Kwanmo Submassif is exposed area over 3,000 km2, and it extends northward into China, where it is called the Bailiping-Gaoling batholith. This batholith shows a wide range of lithological types, including gabbro, through diorite, biotite granite, granodiorite and monzogranite. Among the eight dated samples, one foliated granite and one biotite granite yielded Paleozoic U-Pb zircon ages of 265 ± 2 Ma and 263 ± 2 Ma, and two monzogranites revealed Early Triassic ages of 248 ± 2 Ma and 241 ± 2 Ma, and the remaining 4 samples (diorite, biotite granite, granodiorite and monzogranite) yielded Jurassic ages, ranging from 190 ± 3 Ma to 173 ± 1 Ma. Above age data show that the Guanmobong batholith was a composite one which formed from Late Paleozoic to Jurassic. Similarity, four magmatic stages are distinguished from the Bailiping-Gaoling batholith: Permian (285 ± 6 Ma), Triassic (248 ± 2~245 ± 6 Ma), Jurassic (192 ± 2~170 ± 3) and Cretaceous (119-116 Ma) (Zhang et al., 2004). The main part of the batholith was formed during Triassic to Jurassic. In addition, Jurassic diorite, biotite granite and granodiorite from the Guanmobong batholith are characterized by positive εHf (t) values (4.9 ~ 10.6), fairly young TDM2 (Hf) (500-784 Ma) and uniform O isotopic composition (δ18O: 5.7 ~ 6.9‰) (Fig. 6). Nevertheless, most of the Permian and Jurassic biotite granite and monzogranite present lower εHf(t) values (-10.9 ~ 3.8), older TDM2 (Hf) (889-1651 Ma) and large variation of O isotopic composition (δ18O: 5.6 ~ 9.2‰) (Zhang, Y.B. et al., 2016).


Fig. 6. 
Hf-O isotopes of the zircons for Phanerozoic granitoids in the Kwanmo Massif, Korean Peninsula (after Zhang, Y.B. et al., 2016).

Late Triassic alkaline (syenite) plutons in NK are known as the Phyonggang Complex, which previously thought as formed in Permian, with the K-Ar ages ranged from 300 Ma to 190 Ma (Paek et al., 1996). These plutons mainly distributed in the south margin of the Phyongnam Basin, with minor sporadic exposed in the Nangrim Massif. In the Phyongnam Basin, the Phyonggang Complex are mostly distributed along major faults, and consist of more than ten syenite plutons and some small satellite bodies (e.g., Tokdal, Yonan, Ryeui, Kangbuk, Solhwasan, Sokthandong, Jodoksan), with the total area of about 530 km2. The syenite plutons composed of Na-pyroxene syenite, quartz syenite, nepheline syenite, alkali amphibolite, gabbro, pyroxenite, and kimberlite, with composition changed from sodic to potassic from west to east (Paek et al., 1996). Peng et al. (2016) divided these plutons into the northern (in the Nangrim Massif) and southern (in the Phyongnam Basin) syenite belts. The Pukjin pluton, belonging to the northern syenite belt, shows a U-Pb zircon age of 234 ± 2 Ma (Wu et al., 2007). The Tokdal and Kangbuk Complexes crop out in the Hwanghae province, belonging to the southern syenite belt. The for-mer having an exposed area about 30 km2, is consist of alkali pyroxenite, gabbro, alkali amphibole, clinopyroxene, biotite and/or nepheline syenite. A SHRIMP U-Pb zircon age of 224 ± 4 Ma was obtained from a biotite syenite sample (Peng et al., 2008). The latter having an exposed area about 50 km2, is mostly composed of biotite syenite, with minor quartz syenite and pyroxene syenite. Peng et al. (2016) reported the Triassic age (229 ± 1 Ma, SIMS U-Pb) of the biotite syenite. In generally, these syenite plutons formed at ca. 234-220 Ma.

4.2 Jurassic rocks

The Jurassic granites are well developed in NK, with the ages ranged from 199 Ma to 163 Ma (Table 1). Early Jurassic granites are mostly exposed in the Tumangang Belt and Kwanmo Submassif, and Middle Jurassic granites are mainly distributed in the central KP (Fig. 3).

The Tumangang Belt and Kwanmo Submassif were characterized by large volumes of granitoids, which are known as the Tumangang Complex (Paek et al., 1996). New age data indicate that these granites were mostly emplaced during the Early Jurassic (199-183 Ma), which differs greatly from the previous view that most of them were in the Late Permian and Early Triassic age (Paek et al., 1996). Representative plutons are the Daedokri, Wonsanki, Gongsim, Sungam, and Musanri plutons. The rock types include diorite, quartz diorite, granodiorite, and biotite granites. These granites are I- and highly fractionated I-types, and most rocks belong to high-K calc-alkaline (Zhang, Y.B. et al., 2016). Zircons from these Jurassic granites are characterized by positive εHf(t) values (+4.7 to +13.5), relatively young TDM2(Hf) model ages (784-367 Ma), and uniform O isotopic compositions (δ18O = 5.7‰-7.4‰) (Zhang, Y.B. et al., 2016) (Fig. 7). Such Hf-O isotopic characteristics are likely indicative of a high proportion of juvenile material in their petrogenesis.


Fig. 7. 
Hf-O isotopes of the zircons for Phanerozoic granitoids in the Tumangang Belt, Korean Peninsula (after Zhang, Y.B. et al., 2016).

In the central KP, the Jurassic granites are also well developed, with the emplacement ages ranged from 191 Ma to 163 Ma. The representative plutons include the Manthapsan, Tanchon, Ragwon, Sampyong-ri, Yangdok, Kosan, and Pukjin-Unsan plutons in the Nangrim Massif and Phyongnam Basin, and the Mulkilri, Kyejong-ri, Kaesong plutons in the Imjingang Belt.

The large Tanchon batholith is considered to be representative of the Jurassic granites, and the “Tanchon Complex-J2” is the terminology used for all the Jurassic granites in the KP (Paek et al., 1996). However, a zircon age of 250 ± 5 Ma was obtained within this granitic pluton, and therefore it has been classified as the Triassic magmatism (Paek et al., 1996). The batholith consists of diorite, fine-grained biotite granite, medium- to coarse-grained biotite granite, and porphyritic biotite granite. New zircon U-Pb ages from 4 samples indicate the Tanchon batholith was a composite one, and mainly formed during Triassic (247-222 Ma) and Jurassic (181-168 Ma).

Most of other plutons also have complex rock types. For instance, the Yangdok pluton consists mainly of biotite granite, two-mica granite, and leucogranite; the Pukjin-Unsan batholith contains abundant rock types, including the diorite, biotite granite, two-mica granite, monzogranite, and syenite. Geochemically, biotite monzogranites from the Kyejong-ri pluton and porphyritic granite from the Yangdok pluton have tetrad REE patterns with large negative Eu anomalies, suggestive of extensive magmatic differentiation (Zhang et al., 2021). Some samples (e.g., the Kosan diorite and Tanchon and Yangdok biotite granites) are characterized by high Ba-Sr and low Y and heavy REE contents, high Sr/Y ratios, and strong light and heavy REE fractionation, which suggest that they are high Ba-Sr granites (Zhang et al., 2021).

In general, the Jurassic granites in the central KP are I-type or highly fractionated I-type ones, with small plutonic shapes or a part of composite batholiths, such as the Tanchon batholith.

4.3 Cretaceous rocks

The Cretaceous granites are distributed mainly in the eastern and western parts of the Nangrim Massif (Fig. 4), with the ages ranging from 127 Ma (granite sample PC-1 from the Pukjin-Unsan pluton) to 83 Ma (Table 1), represented by the Nampho and Kuwolsan batholithes in the west, and the Kosan and Kumgangsan ones in the east.

The Nampho and Kuwolsan batholithes were traditionally thought to be Triassic or Triassic-Jurassic age (Paek et al., 1996). However, recent study reveals that the rock types of the Nampo batholith include diorite, tonalite, monzogranite and syenogranite. Three magmatic stages were distinguished as Triassic (234-215 Ma), Jurassic (174 Ma) and Cretaceous (114-109). Seven samples (dioritic enclave, biotite granite, and porphyritic granite) from the Kuwolsan batholith yield uniform Early Cretaceous ages between 113 ± 2 and 109 ± 2 Ma (Wu et al., 2007), which suggests this batholith were formed in the Early Cretaceous.

The huge Kosan and Kumgangsan batholithes located in the east of NK, and were considered as Jurassic age (Paek et al., 1996). Nevertheless, medium-grained two-mica granite from the Kosan batholith yields zircon U-Pb age of 106±2 Ma, and Quartz diorite and biotite granites from the Kumgangsan batholith yield emplacement ages ranging from 100 Ma to 83 Ma. The ages of the Kumgangsan batholith show that the Late Cretaceous magmatism also occurred in the NK.

Combined with ages of volcanic rocks, the Cretaceous magmatism in NK mainly occurred from 136 to 83 Ma, with an age peak of ~110 Ma.


5. Discussion
5.1 Tectono-stratigraphic correlation between the Phyongnam Basin, Taebaeksan Basin and some Paleozoic Basins in the NCC

It is an important geological issue that the relationship between the Paleozoic strata in the Phyongnam Basin and those in it’s neighboring tectonic blocks, e.g., the NCC. The Paleozoic sedimentary strata are mainly developed in the Hyesan-Rowon and Phyongnam basins in the northern KP, and the Taebaeksan Basin in the southern KP.

The Lower Paleozoic sediments, named the Hwangju and Joseon Supergroups in the Phyongnam and Taebaeksan basins, respectively, are exclusively of marine origin. Their general stratigraphic successions are very similar with each other (e.g., Lee and Lee, 2003; Li et al., 2016; Zhai, 2016; Zhai et al., 2019; Peng et al., 2020), with inner continental shelf carbonate depositional features. The Upper Paleozoic littoral coal-bearing sediments were named the Pyeongan Supergroup in both basins, and the paleoclimate was probably warm and arid with somewhat humid conditions when they were deposited. As a result, many large coalfields were formed, e.g., the Samcheok and Yeongweol ones in the Taebaegsan region, the Ripsok one in the Phyongnam Basin.

The NCC was stable during the Paleozoic. The well-developed Cambrian and Ordovician sedimentary rocks consist predominately of marine carbonate with minor fine clastic rocks (Chen and Qin, 1989). Late Ordovician strata are locally developed, and volcanic rocks from the constituent formations (the Zhaolaoyu, Pingliang, and Jinsushan Formations) yielded the eruption ages ranging from 449 Ma to 466 Ma (Chen et al., 2012; Wu et al., 2014; Wang et al., 2015). After a depositional hiatus in the Early Carboniferous, the NCC subsided again and then transgressional marine sediments with coal-bearing clastics and continental clastics deposited during the Late Carboniferous and Permian, respectively. The Late Paleozoic strata are the Benxi and Taiyuan Formations with Late Carboniferous age, whereas the Shanxi and Xiashihezi Formations are Early Permian strata, and the Shangshihezi and Shiqianfeng Formations are Late Permian strata (Chen and Qin, 1989).

Detail comparative studies show that the NCC (the Western Hill and Dalian basins in Beijing and Liaodong Peninsula, respectively) and the KP (the Taebaeksan and Pyongnam basins) have similar Paleozoic stratigraphic sequences (Zhai et al., 2007 and references therein). Furthermore, detrital zircon age spectra for representative Paleozoic sequences in the Pyongnam Basin, Taebaeksan Basin, Imjingang Belt, and the NCC show similar features, suggesting that the KP and NCC may share congruous provenances evolutional history during the Paleozoic (Zhang et al., 2018).

5.2 Tumangang Belt: a part of the Central Asian Orogenic Belt

The Tumangang (Domangang) Belt, situated in the northeastern part of the KP, was regarded as the southeastern extension of the eastern Central Asian Orogenic Belt (CAOB) (Paek et al., 1996; Kim, 2012; Zhang, X.H. et al., 2016; Zhang, Y.B. et al., 2016), or called the Hambuk Block comparable with the Jiamusi Block in the NE China (Lyang et al., 2009; Kim et al., 2012). This belt is characterized by the Late Paleozoic low-grade metamorphic volcano-sedimentary strata (Tumen Group) and granites. The mafic-ultramafic Chongjin Complex in this belt was considered as the ophiolite (Paek et al., 1996), and consists of a rock assemblage of peridotite, clinopyroxenite, gabbro, gabbroic diorite, hornblendite and doleritic dykes. Moreover, zircon SIMS U-Pb dating on distinct rock units document a prolonged emplacement ages from ca. 250 to ca. 170 Ma (Zhang et al., 2019). In addition, they exhibit a compact elliptical geometry, with linear array of stock clusters and crude lithological zonation from cores of peridotites to margins of hornblendites and gabbroic rocks. Furthermore, their geochemical characteristics are very similar to those of the classic Phanerozoic Alaskan-type complexes, e.g., SiO2 ranged from 39.4% to 57.4%, enrichment in light rare earth elements (LREE), depletion in high field strength elements (HFSE), whole- rock (ISr(t) = 0.703062 to 0.705507, εNd(t) = +3.80 to +12.2) and εHf(t) values from + 12.5 to + 24.8, and zircon εHf(t) values from -17.3 to +12.8 and δ18O from 4.92 to 10.4 ‰ (Zhang et al., 2019). Above features indicate the Chongjin Complex belongs to the Alaskan-type complexes, and their petrogenesis most likely involved precursory metasomatism of mantle peridotites by melts from subduction-related sediments with subsequent partial melting.

Large volumes of granitoids distributed in the Tumangang Belt, and the plutons extend into the Kwanmo Massif. The Jihei (Jilin-Heilongjiang) Orogenic Belt, part of the CAOB, which is connected with the Tumangang Belt, also distinguished by extensive distribution of Phanerozoic granites and volcanic rocks. Our age data show that the Phanerozoic magmatism in the Tumangang Belt can be divided into three stages, i.e., Late Permian (265-263 Ma), Early Triassic (248-240 Ma) and Early-Middle Jurassic (199-173 Ma). From the presently available data, the granites in the Jihei Orogenic Belt show a broadly similar chronological sequence at 285-230 Ma, 228-150 Ma and 130-110 Ma, and the Triassic and Jurassic granites distributed all over the area, occupying about 95% of the exposed granites. Consequently, we may infer that the Triassic and Jurassic magmatism took place synchronously across these tectonic units. Furthermore, these granites have the similar mineralogical and geochemical features; e.g., i) most of granites are I- and high fractionated I-types and belong to high calc-alkaline series, ii) although granites located in the north margin of the NCC (or the Nangnim Massif) yield relatively lower εHf(t) values and older TDM2 ages, most others display positive εHf(t) values and fairly young TDM2 ages. Such Hf isotopic characteristics of these granitoids are likely indicative of a high proportion of juvenile material in their petrogenesis. Overall, above similarity between granites in the Jihei Orogenic Belt and those in the Tumangang Belt suggested that the Tumangang Belt is a part of the CAOB.

5.3 Tectonic implications of Triassic granitoids in North Korea

The Triassic granitoids in NK can be divided into two groups: east-west-trending alkaline rocks (234-220 Ma) at the south margin of the Phyongnam Basin, and calc-alkaline igneous rocks (248-211 Ma) in the Nangrim Massif. These Triassic granitoids, especially alkaline rocks, have been considered to be formed in Syn- to post-collisional tectonic setting after collision between the North and South China blocks by some studies (e.g., Chough et al., 2000; Peng et al., 2008, 2016; Seo et al., 2010). However, Triassic granitoids are mainly distributed in the south part of the Dabieshan-Sulu Orogenic Belt, and the alkaline and gabbroic intrusive bodies (the Jiazishan complex) only outcropped in east margin of the Sulu Orogenic Belt and yield little younger isotopic ages of ~211-205 Ma (Guo et al., 2005). Furthermore, the basement of different massifs (the Nangrim, Gyeonggi and Yeongnam Massifs) are closely correlated to the NCC, and the Paleozoic basins in the KP have a similar Paleozoic tectono-stratigraphy to those in the NCC. These geological observations indicate that the NCC and KP might share congruous tectonic history in the Paleozoic (Zhai, 2016; Zhai et al., 2019), and further inferences that the Hongseong Complex might be an allochthonous tectonic slab and not the tectonic zone cut cross the KP (Zhai et al., 2007, 2016, 2019). Therefore, the influence of the continental collision between the North and South China blocks on the KP may be a local and not be as intensive as previously thought.

It should be noted that the Triassic granitoids are widespread in the NCC (Fig. 8). In addition, the Triassic alkaline rocks are distributed in east-west-trending belts along the north margin of the NCC, while calc-alkaline igneous rocks are mainly in the eastern NCC (Zhai, 2016; Zhai et al., 2016, 2019; Wu et al., 2019). By comparison in petrological observations, chronology and geochemical features, the Triassic granitoids and igneous rocks in the KP and NCC indicate that they were most likely formed in the same tectonic setting. Previous studies on the Triassic granitoids in the NCC proposed different models. While two main models ascribed them to post-orogenic extension related to the CAOB or the Sulu Belt, a third one resorted to intracontinental rifting within the NCC (e.g., Zhang et al., 2009; Yang et al., 2012; Wu et al., 2018; Zhu et al., 2020). The first model advocated the continuation of the CAOB orogeny until the Late Triassic. However, some geological and chronological data indicate that the CAOB orogenic event might have ended before the Permian, with the granite-alkaline-gabbro belt in the northern margin of the NCC representing a rift type. Other studies suggested that the Triassic magmatic rocks are related to the Dabie-Sulu orogeny (Oh and Kusky, 2007; Peng et al., 2016). However, since the 250-230 Ma granite-alkaline granite-gabbro rocks are widely distributed from the north through the middle to the south of the KP, and are older than the Jiazishan complex in the eastern Sulu belt, this makes them incompatible with the Sulu orogenic belt (Zhai et al., 2016b, 2019). Therefore, this favored the intracontinental rifting model. In a word, the same tectonic regime may serve as one of the mechanisms for forming the Triassic granitoids in both NK and the NCC. Given the tectonic position of NK in the Triassic, the formation of Triassic igneous rocks in the KP should be influenced by surrounding blocks including the South and North China blocks as well as the Pacific plate.


Fig. 8. 
Distribution of Triassic magmatic rocks in the NCC and KP (modified from Peng et al., 2016; Zhai et al., 2016).


6. Summary

1) The Phyongnam Basin comprises the Lower Paleozoic Hwangju Supergroup (Hwangju and Bopdong Groups/bottom up: ca. 521-467 Ma) and Upper Paleozoic Pyongan Supergroup (ca. 331-242 Ma). δ13C values in the Cambrian Hwangju and lower Bopdong Groups fluctuated relatively little (-4.7~+2.4), but frequently. The three carbon excursions in the upper Junghua-Hukgyo Formations (positive), lower Rimchon Formation (negative) and the middle Kophung Formation (positive) are comparable to the global events of the mIngxinsi carbon isotopic excursion, redlichiid-olenellid extinction and Steptoean positive carbon isotopic excursion, respectively.

2) The Imjin Group tectonically deposited on the Late Mesoproterozoic to Ordovician sequences on the southern margin of the basin and the Imjingang Belt. The group consists of the Anhyop, Puap and Sannyong Formations, in ascending order. The youngest detrital zircon ages (~400 Ma) and Upper Devonian Famennian standard fossil assemblage in the Puap Formation, indicating it’s deposition during the Late Devonian period. The Puap Formation has similar detrital zircon age spectra to those of representative Paleozoic sequences in the Pyongnam and Taebaeksan Basins of the KP and Paleozoic basins in the NCC, indicating that the NCC and KP might experience similar tectonic evolution, and the Imjingang Belt might not be the eastward extension of the Qinling-Dabie-Sulu Collisional Belt.

3) The Upper Paleozoic Tuman Group is well developed in the Tumangang Belt and Kwanmo Massif. It is a Late Paleozoic volcano-sedimentary strata, with SIMS mafic zircon U-Pb age of 257 Ma.

4) The Mesozoic sedimentary strata are mostly developed in continental faulted basins, and consist of the Lower Jurassic Taedong, Upper Jurassic-Lower Cretaceous Jasong, and Lower-Upper Cretaceous Taebo Systems. New age data show that the volcanic activity was significant in NK during the Early Cretaceous in the interval of 136-110 Ma.

5) The Phanerozoic magmatism in NK can be divided into three geochronological stages, i.e., 265-213 Ma, 199-163 Ma and 136-83 Ma, respectively. Among them, the former two are comparable to those in SK. Whereas, the Cretaceous magmatism has a southward younging trend from NK to SK, and Early Cretaceous magmatism (136-110 Ma) are absent in SK.

6) The age patterns and geochemical features of the Phanerozoic granites in the Tumangang Belt are similar to those of the Jihei Orogenic Belt. And therefore, the Tumangang Belt has been suggested as a part of the CAOB.

7) The Triassic granitoids in NK can be divided into two groups: east-west-trending alkaline rocks (234-220 Ma) at the south margin of the Phyongnam Basin, and calc-alkaline igneous rocks (248-211 Ma) in the Nangrim Massif. These granitoids show similar characteristics in petrology, chronology and geochemistry to those in the NCC, indicating that they may share the same tectonic setting.


Acknowledgments

We are grateful to our cooperators from Democratic People's Republic of Korea, Prof. Hyo Nuk Park, Jong Hyok Yang and Jong Nam Kim for their organization of the field excursion and assistance in sample collection. The final version of the paper has benefited from the perceptive comments of two anonymous reviewers and the Editor. This research was supported by the National Science Foundation of China (Grant Nos 41573048, 41890834 and 41530208).


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